BONDING--A PRACTICAL APPROACH

Mostly for atoms in the first (n=1) and second (n=2) periods

(resonance structures not included)

Please add your own notes and examples.

ATOM

Valence/

e’s Needed

Bonding?

Bonding?

Lone pairs?

Formal Charge?

H

 

 

 

1

1 more needed

One single bond

-H

No multiple bonds

Never!

Zero

F

(Cl, Br, I)

 

 

 

7

1 more needed

One single bond

-F

No multiple bonds

Three

Zero

O

(S)

 

 

 

 

6

2 more needed

2 single bonds

-O-

FC = 0

1 double bond

=O

FC = 0

Two

Single bond and 3 lone pairs for O-

FC = -1

N

 

 

 

 

 

5

3 more needed

3 single bonds and 1 lone pair

1 single and 1 double with 1 lone pair

1 triple bond with a lone pair

1 lone pair,

FC = 0

N+

 

 

 

 

 

 

4 single bonds,

FC = +1

1 triple and 1 single bond, FC = +1

2 double bonds,

FC = +1

0 lone pairs

FC = +1

C

 

 

 

 

 

4

4 more needed

4 single bonds

2 single and 1 double bond

Never!

 

(except CO)

FC = 0

(almost always)

C

 

 

 

 

 

 

2 double bonds

1 triple and 1 single bond

 

FC = 0