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Chemistry 103/113 Laboratory |
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This Week |
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Expt 6: Photochemical Blues (week 2) o
Week 2 report due
tomorrow |
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Next Time |
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Expt
6: Photochemical Blues (week 3) ·
Quiz 4: Expts 4, 8 |
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Notes for Today |
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Photochemical Blues (Week 2) ·
Overview: o
Synthesize/purify
K3Fe(C2O4)3.3H2O (“Green Compound”) (Week 1) o
Qualitative tests
for K+, Fe3+,
C2O42- (Week
2) o
%Fe photoreduction
assay (Weeks 2,3) o
Make
blueprints (Week 3) ·
Qualitative
Tests of the Green Compound: o
Precipitation
tests for Fe3+ and C2O42- o
Flame test for K+ §
heat excites
electrons to high E levels §
as electrons drop
back to lower E levels, photons of light are emitted
§
light color
emitted is determined by element’s
electron E level spacings color
emitted depends on the element
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Quantitative
Analysis of the Green Compound for Mass %Fe3+:
o Today §
Weigh green solid, dissolve,
expose to light o Next Time § Collect and weigh the FeC2O4.2H2O produced from green solid § Find moles FeC2O4.2H2O
produced § Find moles Fe3+ present
in the green solid § Find grams Fe3+in
the green solid ·
Safety
Issues o
Splash hazard. Goggles required.
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