Chemistry 104 Laboratory

 

 

This Week

Answer Keys

Gen Chem Lab

Periodic Table

 

 

 

á       Expt 1:  Brita, Scum, and Scale (Week 2)

o      Complete Parts B, C, D with your group

á       Report

o      Procedure for B, C, D due today

o      Data for B, C, D.1 (Excel spreadsheet, log sheet) due today

o      Week 2 Worksheet with Part B Excel graphs due in two days

 

Next Time

á       Expt 1:  Brita (Week 3)

o      Thermodynamics of a Rubber Band

á       Quiz 3:  Expt 4

 

Notes for Today

 

  • The Brita Filtration Process

Cation exchange on the filter:

2(R-SO3-)(resin cation)+(s) + M2+(aq) -->

               (R-SO3-)2 M2+(s) + 2(resin cation)+ (aq)

 

  • Questions We Want To Answer About Brita Water Softening
    • Is the Brita filter effective in softening tap water (removing Ca2+, Mg2+)?
    • Does the softening capacity change over time?
    • What is the cation exchange chemistry? What are the resin cations?

 

  • To Answer These Questions You Must
    • Identify the cations present in unfiltered tap water
    • Identify the cations left in the water after Brita filtration
    • Identify any cation concentration changes caused by filtration

 

  • Analytical Tools For The Job
    • EDTA (Y4-) Titration

 

M2+(aq) + Y4-(aq) --> MY2-(aq)

 

      • Used to measure [M2+] in unfiltered water
      • Endpoint detection by spectrophotometry
      • What information is used to calculate [M2+]?

 

    • pH Measurement
      • Use to decide if H+ is a resin cation
        • Is more H+ present after filtration than before?
      • Review:  The pH Meter

 

    • Ion Chromatography
      • Use to measure [M2+] in unfiltered tap water
        • Same result as EDTA Titration?
      • Use to measure [M2+] in filtered tap water
        • Is Brita filter effective in softening water (removing  M2+)?
      • Use to identify resin cation(s) in filtered water
      • Use to measure [resin cation] in filtered water