Chemistry 104 Laboratory

 

 

This Week

Answer Keys

Gen Chem Lab

Periodic Table

 

 

 

á       Expt 3:  Understanding and Predicting Acid-Base Behavior

á       Do Part A of Expt 2 (if time permits)

á       Check In

á       Get check in sheet now, key in lab

á       Wait to do check in until after you finish Expt 3

 

Next Week

á       Expt 2:  A Cycle of Copper Reactions

 

Notes for Today

What is pH? 

á       A combination of

á       p for the word power

á       H for hydrogen ion

á       A measure of acidity

á       pH = -log10[H+] or -log10[H3O+]

á       Most aqueous solutions have pH values in the range 0-14:

         

How is pH Measured?

á       Use a pH Meter

á       measures potential difference (voltage) between two electrodes

o      potential of sensing electrode (glass electrode) depends on [H+]

o      reference electrode potential is independent of [H+]

o      potential difference (voltage) depends on [H+] of solution

á       can measure to +/- 0.01 pH unit

á       combination electrode (glass + reference in one unit) is common

á       More about pH and pH meters

á       Use an Indicator

á       H2O + HIn <--> H3O+ + In-

á       color depends on pH

o      HIn and In- are different colors

á       e.g., for bromthymol blue,

á       HIn = yellow and In- = blue

á       when both HIn and In- are present, transition color (green) occurs

 

á               transition occurs over a fairly wide range (~2 pH units)

How Can a Salt Affect pH?

á   Add NaNO3 to water; pH = 7

á   Add CH3NH3NO3 to water; pH <7

á   Why not the same?

o      identify ions in solution

o      identify ions that do/don't hydrolyze (react with water)

o      write a net ionic equation to explain why the pH in CH3NH3NO3 solution is <7

¤       reactants = ion, H2O

¤       products = H3O+, ???

Practical Details

á       Work with a partner

á       Safety

o      Goggles required throughout

á       Time Management

o      Limited number of pH meters, so you may need to complete lab out of order

Expt 3 Report

á       Purpose, Procedure, Data section due today at end of lab

á       See Writing Your Report for remaining requirements

á       Due in two days, 9 p.m., TA folder outside 184

Need help?  See/email KDL or see a TA